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There is no simple yes/no answer and it does depend on versions. If you save the Calc spreadsheet in the default for Calc, the Open Document Format .ods, then MS Excel 2010 or later is required to open this format. A simple check by the user of Excel is if they can save a spreadsheet in .ods then they can open it. Otherwise you will need to save the Calc spreadsheet in Excel format, which is an option in the Calc save dialogue. There is however no guarantee of complete compatibility.