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(Modified my comment to an answer)

You may try the → OKDict extension (up to LibreOffice 3.6.x).
A stand-alone alternative: → GoldenDict · dictionary lookup program.

See also:
Bug 35313 - [Task] Improve Hyperlink Bar
→ http://nabble.documentfoundation.org/Hyperlink-Toolbar-tc3976926.html#a3980367