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To begin, StarOffice isn't around anymore (the last release was in December 2010 under Oracle OpenOffice). Even if you did get a copy, it wouldn't be up-to-date with newer UI, and possibly some features.

Apache OpenOffice and LibreOffice are both derivatives of the code from Oracle OpenOffice (the successor to Star Office). The biggest differences between the two are going to be how frequently LibreOffice is updated (which is far more) in comparison to OpenOffice. Those who value constant update and new features/tools would prefer LibreOffice. And, from what I've found, LibreOffice appears to have better adoption by individuals, as well as commercial organizations which should count for something when making your decision.