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Is it possible you have changed the application associated with this file type?

From Right click/Open with, Choose default program..., select More options at the bottom of the list of applications.

If LibreOffice application is not available in the list then select "Look for another app on this PC" and browse to the location of the LibreOffice application.

Note the checkbox "Use this application for all .rtf files" if you want to always use this application for files of this type.