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STARTS Microsoft Office 2010 will complain that ODF 1.2 and extended documents written by LibreOffice 3.5 are invalid (but opens them still). This is a shortcoming in MSO2010 only supporting ODF 1.1, please see here for further details ENDS

Many thanks for this solution which has solved my problem in saving in .odt format.

However I still have a problem in MS Office Word 2010 not opening files saved by LibreOffice using Microsoft Word 97/2000/XP/2003 (.doc)(*.doc) format.

Would appreciate further assistance.