Libre Office says it has stopped working and closes when I try to print?
What version of LibreOffice are you running? If not 4.0.1, I would try updating.
You are likely using an older version of LibreOffice. Try updating to the latest version, 4.0.3 and see if the problem persists.
I had the same issue with one of the users. After hours of searching on the internet and many many Installations of LO 3.6.5 & 4.0.1 , I finally found the solution. This issue is due to printer driver.
So you could try;
Try to do a test print from the same printer but from another application, just to make sure printer is ok.
If possible try to install latest driver for that printer or remove the printer and add it again.
I hope this will be of any help to you…