envelope printing
Mail merge help
https://help.libreoffice.org/6.1/en-US/text/swriter/guide/form_letters_main.html?DbPAR=WRITER#bm_id3159257
And choose paper feed as envelope in printer
Hello,
You can create and enter data for envelopes (or use mail merge for multiple envelopes). In Writer, from the menu select Insert->Envelope
(may need to scroll down the list - it is second from bottom). In the dialog presented you can enter the information, use data from a database (mail merge) and set the envelope size.