LibreOffice 4.1.4.2 will not install

The error always in a file in C:\Config.msi, one of the RBF files with an internal error.

Please provide more details. I assume you are using Windows, but what version? What is the exact error? When does it occur, in the first screen of the installation wizard, at the end or somewhere in between? Do you have the rights to install software, i.e. are you an administrator on this computer?