Previous version of libra office would print. New download will not print. Other PDF files will print.
Ok - and what is your actual question?
Your statement, which unfortunately contains no question, is very rudimentary.
Is it true that you can print with one version of LibreOffice and not with another?
What has changed since then?
To limit a problem, minimum information is required here.
Which operating system do you use?
Which LibreOffice version did you print with?
With which LibreOffice version is printing no longer possible?
Did you choose the right printer?
See also: https://wiki.documentfoundation.org/Ask/Getting_Started