Libre Office installation failure: Error Insufficient disc space"

Actually File Explorer shows there is 730GB available on the hard drive.

Could do with a bit more detail on what it is you’re actually doing when you install. However, for what it is worth:

This happens to me on Win7 if I try to do a totally new install of Firefox to a pre-existing folder that I created myself. Would suggest if you are trying to install to a folder you created before attempting the install then delete that folder and use the LibreOffice installer’s own routine to install to a folder of your own choosing. Or, in other words, create your new folder as part of the install routine (do not create it before trying to do the install). What I mean is that when you get to the part of the install routine that suggests a path and folder to install to just modify that path to suit what you really want (and if, as part of doing that, you install to a folder other than what the installer was going install to then the install routine should create the folder you want). I’d try that and see if it works.

If it does work please post back here with the info - that will help others in the long run.

(If the hints by @Radish didn’t solve the issue:)
Installing software under Win going the default way, you need sufficient disc space in “C:\ Program Files” (64 bit LibO) or “C:Program Files (x86)” (32bit) (and very few in some additional locations).
If you have a configuration with a C: partition (and a data partition) or with a dedicated harddrive for C: LibO will only use the space there for installation - and fail if not finding enough. Free space on another partition / disk will not help except you choose to break the default.
Different but similar on Linux.