After I save the document and click print, the document saving page opens and I need to name it again. I can SEE the Doc saved in the list and yet it will not print. I save it again and no still printing happens.
It is possible that you have some virtual printer selected by default, that “prints” to a file (like PDF). So, when you click “Print” toolbar button, you print to default printer (without seeing Print options), and you see that printer’s Save As dialog, not LO’s.
You may use File->Print to open Pring dialog, where you can see what printer you use.