Does Libre have an email service?
Do you mean an E-mail Client? I am using the free Thunderbird email client. It works fine with the LO.
To get an integrated eMail client we only need to downdate 25 years.
StarOffice by StarDivision (“Do everything in one place!”) had one - and the “StarDesktop” which captured the Win (3.11? 95?) desktop.
BTW: It was programmed so cleanly that it still can run under my Win 10.
Or was just MS too sleepy to spoil everything?
Imho it is possible to create serial mails.
.
Maybe you should explain “service”…
Like hotmail or webmail.
These are not email CLIENT softwares. LibreOffice works with the email client softwares. Install one onto your PC.
I suggest you to install the Thunderbird.
LibreOffice can deliver through your email service for mail merge assuming it is a simple protocol for the service. It might not work with Gmail or other services.
It is often better to mail merge emails through your normal email client
Thank you that’s all I need to know.
So you question is: Can I have an email-address lik Carlton@libreoffice.example ?
Then the answer is: No LibreOffice/TDF offers no mail-service for users of the office-suite.
Heh, the answer is: TDF members can get a @libreoffice.org email, but yes, that’s not what OP asked for 
I guessed so, therefore I added the “for users of the office-suite.”
( and obviously TDF members are allowed to be users also…)
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