i’m unable to use single curly/curling quotation marks with times roman font in writer. i used to be able to up until recently. the libre Version i’m using is 4.4.6.3
Choose menu Tools - AutoCorrect - AutoCorrect Options… - Localized Options tab, and check Replace below Single Quotes. See, pressing in both buttons, if Start quote and End quote are the curly ones.
Then choose menu Tools - AutoCorrect, and select While typing (almost certainly the problem is here).
Tested in LibreOffice 6.3.6.2 (x86); OS: Windows 6.1.
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