First delete all tab stops in one paragraph:
- Place the cursor in one paragraph.
- Choose menu
Format - Paragraph… - Tabs, press Delete All and OK.
Next, delete all tab stops in the other paragraphs:
- Select (at least part of) all the paragraphs from which you want to remove the tab stops.
- Choose menu
Edit - Repeat: Apply atributes (same as Ctrl+Shift+Y).
Now, set the new tab stops:
- Select (at least part of) all the paragraphs in which you want to set tab stops.
- Choose menu
Format - Paragraph… - Tabs, select Position and Type, press New and OK.
More LibreOffice Help on Tabs.
Also consider working with Styles. They can save you a lot of work.