In Writer, when I select File, New and then Labels the program locks up. No Labels, just Not Responding. Windows 7 Pro 64, English. LibreOffice Version 4.2.6.3, English
Writer starts fine. But still no Labels, everything just quits
Just reset user profile and good to go
Does Writer start from this screen by clicking at Writer?
If not I would try to reset the user profile. For details please refer to https://wiki.documentfoundation.org/UserProfile