I am using ver 6.1 with Win 10 and I’ve had this problem a long time with this and previous versions and have been searching for a solution. It has not changed over multiple OS updates. I have a 111 page document, (22 figures, ~200 equations, 2.3 MB) that will save normally upon first opening Writer. After that the application will go into the Not Responding (freeze) state right after the green bar finishes. This will start being 5 seconds long and the duration will progress to 5 minutes, 10 minutes, who knows what the limit is. I have to shut down the app and restart and for the first few saves I can tolerate the waiting. I can have a one page document open simultaneaously and the issue does not occur with the shorter document. While in the freeze state, the shorter document is unsurprisingly not accessible. I have not seen this behavior described on here, my apologies if it has been resolved without my seeing it.
Version: 6.1.4.2
Build ID: 9d0f32d1f0b509096fd65e0d4bec26ddd1938fd3
CPU threads: 4; OS: Windows 10.0; UI render: default;
Locale: en-US (en_US); Calc: group threaded