I’ve got round this glitch by reverting to a (Samsung Recovery Solution 4) image of my system that didn’t have any LibreOffice installed, and then installing v4.0.0 from there.
Either there was a problem in my system, or LibreOffice v4.0.0 doesn’t install completely well over previous version.
(I then noticed that my usual trick of replacing user profile folder’s config sub-folder & registrymodifications.xcu file (this time from my working LibreOfficePortable v4.0.0 instance containing all of my personal settings) doesn’t bring across my settings as it should, so I’m having to reset my fully installed version of LibreOffice the long way.)